长期施肥与土壤性质对水稻土磷吸附的影响
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国家自然科学基金项目(41401234,31660596);江西省自然科学基金项目(20151BAB214007,20161BAB213080);国家重点研发计划(2017YFD0301601)。


Effects of longterm fertilization on phosphorus sorption and soil properties in paddy soil
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    摘要:

    基于长期定位试验(始于1981年),采用磷等温吸附试验方法,研究了不同施肥措施(包括无肥、单施化肥、稻草还田、沼肥)及相关土壤性质对耕层水稻土(0~15 cm)磷吸附特性的影响。结果表明,等温吸附试验中,不同施肥处理的水稻土,随着磷浓度的增加,磷的吸附量逐渐增大。对磷等温吸附曲线,用Langmuir方程拟合效果比Freundlich和Temkin方程好,各处理拟合优势度均在0.99以上。基于Langmuir方程计算,土壤磷最大吸附量(Xm)大小顺序为沼肥>稻草>单施化肥>无肥,且沼肥处理显著高于其余3个处理(P<0.05);同时,沼肥处理的磷吸附饱和度亦显著高于其它处理,但处理间土壤磷吸附常数与磷最大缓冲容量无显著差异。Xm值与土壤草酸浸提态磷(P-ox)、无定型铁(Fe-ox)、无定型铝、交换态钙、镁的含量有较高的相关性,其中与P-ox、Fe-ox的相关性最显著,相关系数分别为0.95(P<0.01)、0.64(P<0.05);主成分分析表明,无定型铁、铝与交换态钙、镁是引起不同施肥处理磷吸附差异的主要因素。与无肥及单施化肥相比,长期施用沼肥显著提高了土壤无定型铁、铝的含量(P<0.05),从而增强了土壤磷吸附能力。

    Abstract:

    The effects of longterm different fertilization practices(initiated in 1981)and resultant changes in soil properties on phosphorus(P)sorption characteristics were studied using P sorption isotherm experiment.We selected 12 soil samples at depth of 0~15 cm from a longterm field trial with four fertilization practices including no fertilizer(CK),only application of chemical fertilizer,straw retention,and biogas slurry incorporation.The results showed that the amount of sorbed P increased with initial added P concentration increasing.The Langmuir equation was more ideal than Freundlich and Temkin equations in fitting the P sorption isotherm,which had determination coefficients greater than 0.99 for all treatments.Biogas slurry incorporation had the greatest Langmuir P sorption maximum(Xm),which was significantly higher than the other three treatments(P<0.05),followed by straw retention and chemical fertilization treatments,and the lowest in CK.In addition,biogas manure treatment had the highest value of degree of P saturation.However,there were no significant differences in the constant related to the bonding strength and maximum buffer capacity among the four treatments.Oxalateextracted Fe,Al,and P(Feox,Alox,and Pox,respectively),and Mehlich 3extracted Ca and Mg(CaM3 and MgM3)were positively correlated with Xm,especially for Pox and Feox,for which the correlation coefficient was 0.95(P<0.01)and 0.64(P<0.05),respectively.Principal component analysis showed that Feox,Alox,CaM3 and MgM3 contributed mostly to the variation of P sorption characteristics among the four fertilization regimes.Compared with CK and chemical fertilizer application treatments,longterm incorporation of biogas manure increased the contents of amorphous Fe and Al minerals in paddy soil,and thus enhanced soil P sorption capacity.

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洪欠欠,颜晓,魏宗强*,吴建富*.长期施肥与土壤性质对水稻土磷吸附的影响[J].中国土壤与肥料,2018,(3):61-66.

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  • 在线发布日期: 2018-06-25
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