By using the chicken manure and corn straw as the main raw materials，the aerobic composting fermentationexperiments were carried out by addingenzymes.ThepH，EC，heavy metal content andfraction，humus content changesand infrared spectrum characteristics of compost were studied at different temperatures and times.The results showed that compared with pre-composting，the pH value increased with the increase of temperature and time，and the maximumincrease was 0.53units.The EC value first increased and then decreased with the compostingtime，and reached the lowestunder the treatment of85℃.Due to the concentration effect，the content of heavy metals increased to different extents.The maximum increases ofCu，Zn，Cr，Cd and As were35.6%，11.5%，35.0%，35.3% and23.8%，respectively.However，the distribution rate of exchangeable heavy metals was reduced，and the rate of residual fraction of heavy metalswas correspondinglyincreased.Compared with before composting，the immobilization rates ofCu，Zn，Cr，Cd and Asincreased by24.8%，26.0%，27.6%，26.9%，and13.9%，respectively.Under high temperaturetreatment，the contentsof humic acid and fulvic acid were low，and the ratio of HA/FA increased with the increase of compost time andtemperature.However，the amount ofaliphatic，aromaticmatter，carboxylicacid，and polysaccharide wasdecreased.The resultsabove indicated that high temperature(85℃)not only accelerates the compost fermentation process，but also effectivelyimmobilize heavymetals，so as to achieve wasteharmlessness.