抑制电导离子色谱法测定大量元素水溶肥料中硝态氮含量
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Determination of nitrate nitrogen in watersoluble fertilizers containing nitrogen,phosphorus and potassium by ion chromatography with suppressed conductivity
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    摘要:

    建立了测定大量元素水溶肥料中硝态氮(NO-3-N)的抑制电导离子色谱分析方法。在优化的色谱条件下,NO-3与水溶肥料中常见的其他阴离子实现了很好的分离。在0~20 mg/L范围内,NO-3的峰面积与其浓度线性关系良好(R2 =0.999 9),相对标准偏差为0.54%(n =7),方法检出限为0.007 mg/L,加标回收率为98.52%~102.10%。样品测定结果与行业标准NY/T 1116-2014进行了比较,结果表明,两种方法的测定结果无显著差异。本方法稳定、可靠、省时且干扰小,适合大量元素水溶肥料中硝态氮含量的批量测定。

    Abstract:

    An ion chromatography method with suppressed conductivity for determination of nitrate nitrogen (NO-3N)in watersoluble fertilizers containing nitrogen,phosphorus and potassium was developed.Under optimized chromatographic conditions,NO-3 was well separated from other anions commonly found in watersoluble fertilizers.The result showed that the calibration curve was linear in the range of 0~20 mg/L (R2=0.999 9).The limit of detection(LOD)was 0.007 mg/L.The recoveries were ranged from 98.52% to 102.10% (RSD= 0.54%,n=7).The results were compared with those by the standard NY/T 1116-2014.It showed that there was no significant difference between the two methods.The established method with no interference is stable,reliable and efficient,and can be applied to the analysis of large batches of watersoluble fertilizer samples.

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毛红祥,桂素萍,肖植特,李玉兰,陈萌.抑制电导离子色谱法测定大量元素水溶肥料中硝态氮含量[J].中国土壤与肥料,2018,(2):176-178.

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  • 收稿日期:2017-05-20
  • 最后修改日期:2017-06-24
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  • 在线发布日期: 2018-04-28
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