不同粒径保水剂对锌肥吸附及缓释性能研究
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(北京林业大学水土保持学院,北京 100083)

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甄倩(1995-),女,山西吕梁人,硕士研究生,研究方向为农业基础科学。E-mail:zhenqian@bjfu.edu.cn。

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基金项目:国家重点研发计划项目(2016YFC0501704);国家科技支撑(2015BAD07B02)。


Study on the adsorption and sustained release performance of zinc fertilizers with different particle size water absorbent polymer
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(School of Soil and Water Conservation,Beijing Forestry University,Beijing 100083)

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    摘要:

    针对锌肥直接使用到土壤中利用率低的问题,选取4种粒径保水剂(M、L、L1和L2),通过吸附与缓释实验研究其对锌的吸附特性及其重复缓释性能。结果表明:采用Langmuir和Freundlich等温吸附方程对4种粒径保水剂的吸附实验数据进行拟合分析,得出4种粒径保水剂适合Freundlich等温吸附模型,为多分子层吸附,且其吸附为适中吸附;保水剂对Zn2+的吸附符合准二级动力学模型(R2>0.99),化学吸附是控制吸附速率的主要因子,其吸附平衡时间为60 min(M)<240 min(L)<1320 min(L2)<1360 min(L1),平衡吸锌量大小顺序为L1>L2>L>M,即L1(4~6 mm)粒径吸附平衡时间较长,最大吸锌量高;保水剂累积释锌量表现为L1、L2>M、L,较大粒径保水剂L1(4~6 mm)、L2(6~10 mm)在相同条件下可以释放更多锌离子,具有更好的释肥效果;FT-IR分析表明高分子保水剂内部官能团的离子交换与络合对于Zn2+的吸附固定起重要作用。综合来看,所供试的4种不同粒径保水剂,从不同浓度溶液中吸肥、释肥性能来看,L1(4~6 mm)粒径保水剂的性能最佳,推荐作为锌肥缓释载体的适宜粒径,可避免直接施锌肥造成土壤中锌的生物有效性低而导致肥料利用率低的问题。

    Abstract:

    In order to solve the problem of low utilization of zinc micro-fertilizer being applied directly into soil,the adsorption characteristics and repeated slow-release properties of zinc with different particle sizes of Water Absorbent Polymer(WAP) were studied.The Langmuir and Freundlich isothermal adsorption equations were used to fit and analyze the experimental adsorption data of the four particle sizes of WAP(M,L,L1 and L2),and the results showed that they were suitable for the Freundlich isotherm adsorption model,which was multi-molecular adsorption,and the adsorption difficulty was moderate.The adsorption of Zn2+ by WAP was fitted by the Pseudo-second-order model(R2 >0.99),which was mainly chemical adsorption.The adsorption equilibrium time was 60 min(M)<240 min(L)<1320 min(L2)<1360 min(L1),the order of equilibrium adsorption was L1>L2>L>M,that is,L1(4~6 mm) particle size had the longest equilibrium time and the highest zinc adsorption capacity.The cumulative zinc release of the WAP is expressed as L1,L2>M,L,larger-diameter water-retaining agent L1(4~6 mm)and L2(6~10 mm)released more zinc ions under the same conditions and had better fertilizer release effect.FT-IR analysis showed that the ion exchange and complexation of the functional groups in the WAP played an important role in the adsorption and fixation of Zn2+.Taken together,among the four kinds of WAP with different particle sizes tested in this article,the WAP with a particle size of 4 to 6 mm(L1)has the best performance from the perspective of absorption and release of fertilizers in different concentrations of solutions.It is recommended as a zinc fertilizer slow-release carrier to avoid the problem of low bioavailability of zinc in the soil caused by the direct application and low fertilizer utilization.

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甄倩,王百田.不同粒径保水剂对锌肥吸附及缓释性能研究[J].中国土壤与肥料,2021,(3):257-263.

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  • 收稿日期:2020-03-25
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  • 录用日期:2020-05-12
  • 在线发布日期: 2021-07-29
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