福建农田常用商品肥重金属含量分析及评价
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(1.厦门华厦学院环境与公共健康学院,福建 厦门 361024;2.环境监测福建省高校重点实验室,福建 厦门 361024;3.厦门市环境监测工程技术研究中心,福建 厦门 361024)

作者简介:

林承奇(1991-),硕士,讲师,从事环境监测与评价研究。E-mail:linchengqia@163.com。

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基金项目:

基金项目:福建省中青年教师教育科研项目(JAT200871);福建省水产功能性饲料及养殖环境调控重点实验室开放基金项目(FACE20200007);福建省大学生创新创业训练计划项目(S202212709009)。


Analysis and evaluation of heavy metal contents in commercial fertilizers commonly used in agricultural fields of Fujian province
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(1.College of Environment and Public Health,Xiamen Huaxia University,Xiamen Fujian 361024;2.Key Laboratory of Fujian Universities for Environmental Monitoring,Xiamen Fujian 361024;3.Xiamen Environmental Monitoring Engineering Technology Research Center,Xiamen Fujian 361024)

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    摘要:

    为研究福建省农田常用商品肥中重金属的含量及其风险,采集福建省农田常用商品肥样品,用电感耦合等离子体质谱法(ICP-MS)和原子荧光光谱法(AFS)测定了11种重金属(Cd、Hg、As、Pb、Cr、Tl、Ni、Co、V、Cu和Zn)含量,对比分析不同商品肥中重金属含量分布并依据国家标准限值进行评价。结果表明:氮肥中Tl和Co未检出,而氮肥中其他9种重金属以及其他商品肥中11种重金属均有检出。不同商品肥中重金属含量的差异性较大,Tl和Cr表现为中等变异,其他重金属均表现为强变异。磷肥、有机肥和有机-无机复混肥中的各重金属含量相对较高。有机-无机复混肥中40%样品的As含量超出《肥料中有毒有害物质的限量要求》(GB 38400—2019)规定的限值,而有机-无机复混肥中其他重金属以及其他商品肥中各重金属含量均在限值之内。不同种类商品肥受生产原料的影响使重金属含量差异较大,应从源头上进行严格控制。所研究的商品肥中重金属含量整体上处于安全水平,但商品肥中重金属可能对农田系统产生的风险不可忽视。考虑到重金属的蓄积性,应从重金属含量、施肥方式及施肥时长等方面重点关注Cd、Hg、As和Pb的潜在污染。

    Abstract:

    In order to research the contents and risks of heavy metals in commercial fertilizers commonly used in agricultural fields in Fujian province,the samples of commercial fertilizers commonly used in agricultural fields in Fujian province were collected,and the contents of eleven heavy metals (Cd,Hg,As,Pb,Cr,Tl,Ni,Co,V,Cu and Zn) were determined by inductively coupled plasma mass spectrometry (ICP-MS) and atomic fluorescence spectrometry (AFS). The heavy metal contents in different commercial fertilizers were analyzed and evaluated according to national standard limits. The results showed that Tl and Co were not detected in nitrogen fertilizers,while other nine heavy metals were detected in nitrogen fertilizers and eleven heavy metals were detected in other fertilizers. The heavy metal contents in different commercial fertilizers varied considerably,with Tl and Cr showing moderate variation and all other heavy metals showing strong variation. The contents of heavy metals in phosphate fertilizer,organic fertilizer and organic-inorganic compound fertilizer were relatively higher. The As content in 40% of the samples of organic-inorganic compound fertilizers exceeded the limit values specified in the Limitation requirements of toxic and harmful substance in fertilizers (GB 38400—2019),while the contents of other heavy metals in organic-inorganic compound fertilizers and all heavy metals in other fertilizers were within the limit values. The contents of heavy metals in different types of fertilizers varied greatly depending on the raw materials used in their production and should be strictly controlled at source. The heavy metals in the studied fertilizers were generally at a safe level,however,the potential contamination of agricultural systems caused by heavy metals in commercial fertilizers cannot be ignored. Considering the accumulation characteristics of heavy metals,more attention should be paid to the potential contamination of Cd,Hg,As and Pb in terms of heavy metal content,fertilizer application method and duration of application.

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林承奇,王雯琦,黄华斌,王燕云,王艳.福建农田常用商品肥重金属含量分析及评价[J].中国土壤与肥料,2023,(7):149-155.

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  • 收稿日期:2022-06-08
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  • 录用日期:2022-07-10
  • 在线发布日期: 2023-10-30
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