土壤中硫磺氧化的影响因素
作者:
作者单位:

1.中国农业大学资源与环境学院,绿色智能肥料创新农业农村部重点实验室,植物-土壤相互作用教育部重点实验室,养分资源高效利用全国重点实验室,国家农业绿色发展研究院,北京 100193 ;2.云南云天化股份有限公司研发中心,云南 昆明 650228

作者简介:

刘俊杰(1995-),硕士研究生,研究方向为硫—锌互作的高效肥料设计与验证。E-mail:2950854544@qq.com。

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基金项目:

云南省张福锁院士工作站科技人才与平台计划(202305AF150055);洱海流域农业高质量发展与面源污染防控协同的创新模式构建与示范重大科技专项计划(202202AE090034)


Influencing factors of sulfur oxidation in soil
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1.College ofResources and Environment,China Agricultural University,Key Laboratory of Innovative Agriculture with Green IntelligentFertilizer,Key Laboratory of Plant-Soil Interaction of Ministry of Education,National Key Laboratory of Efficient Utilizationof Nutrient Resources,National Academy of Green Agricultural Development,Beijing 100193 ;2.R&d Center,YunnanYuntianhua Co.,LTD.,Kunming Yunnan 650228

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    摘要:

    通过综述影响硫磺氧化的土壤性质、肥料性质两部分内容,为进一步解决硫磺在土壤中氧化率低的问题, 同时也为高效硫肥的研制提供理论依据。植物对于硫的需求日益增高,硫是作物必须的营养元素,被用来合成许多蛋白质和氨基酸,对植物的产量和品质有极大的影响,同时也在防治害虫、改良土壤性质方面发挥着巨大的作用。由于大气沉降、径流损失以及大量元素肥的过量施用导致硫元素附带输入减少和作物移除量的增加,土壤中硫含量供需不平衡,因此,硫肥添加成为未来的主流趋势。现有硫肥里的硫主要由两种形态组成,分别为单质态的硫磺和化合态的硫酸盐。硫磺廉价易得,在氧化过程中可以产生酸,改良碱性土壤 pH,为更加科学地进行硫肥的研发设计,现需对硫磺在土壤里的主要氧化因素(微生物、pH、温度、湿度、粒径)进行系统的梳理。得到以下主要结论:微生物活性对硫磺的氧化作用要远大于数量,因此,影响微生物活性的土壤 pH、温度、湿度等是极为重要的因素,微生物的种类在其中发挥的作用比重尚无绝对的定论。大多数研究表明,硫磺的氧化速率随土壤 pH 的降低而降低,在 30 ~ 40℃且土壤含水量接近田间持水量时硫磺氧化速率最快。而硫磺粒径与氧化速率呈反比是确定的,其本质是微生物定殖于肥料颗粒的表面积起主导作用,并且受在土壤里的扩散影响,粉状硫磺相对于颗粒状硫磺更易于氧化。

    Abstract:

    The properties of soil and fertilizer affecting sulfur oxidation were reviewed to further solve the problem of low sulfur oxidation rate in soil,and to provide theoretical basis for the development of high efficiency sulfur fertilizer. Plant demand for sulfur is increasing. Sulfur is a necessary nutrient element for crops,it’s used to synthesize many proteins and amino acids, and has a great impact on the yield and quality of plants. It also plays a huge role in controlling pests and improving soil properties. Due to atmospheric subsidence,runoff loss,and excessive application of nitrogen,phosphorus and potassium fertilizers,the incidental input of sulfur is reduced and the amount of crop absorption is increased,and the supply and demand of sulfur content in soil is unbalanced. Therefore,the addition of sulfur fertilizer has become the mainstream trend in the future. The sulfur in existing sulfur fertilizers is mainly composed of two forms,namely,elemental sulfur and combined sulfate. Sulfur is cheap and easy to obtain,and can produce acid in the oxidation process to improve the pH of alkaline soil. In order to conduct more scientific research on the development and design of sulfur fertilizer,it is necessary to systematically review the main oxidation factors of sulfur in soil(microorganisms,pH,temperature,humidity,particle size). The main conclusions were as follows:The oxidation effect of microbial activity on sulfur was much greater than that of quantity. Therefore,soil pH,temperature and humidity that affect microbial activity were extremely important factors,and there was no absolute conclusion on the role of microbial species in the proportion. Most studies showed that the sulfur oxidation rate decreased with the decrease of soil pH,and the sulfur oxidation rate was the fastest when the soil moisture was close to the field water capacity at 30-40℃ . The inverse relationship between sulfur particle size and oxidation rate was confirmed,the essence of which was that microorganisms colonization on the surface area of fertilizer particles played a leading role,and affected by diffusion in the soil. Powdered sulfur was easier to oxidize than granular sulfur.

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刘俊杰,祝园园,鲁振亚,黄成东,王芳,刘文彪.土壤中硫磺氧化的影响因素[J].中国土壤与肥料,2024,(5):206-211.

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  • 收稿日期:2023-06-27
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  • 录用日期:2023-08-21
  • 在线发布日期: 2024-07-30
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