添加不同辅料对猪粪堆肥重金属钝化效果的影响
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(河南科技大学农学院/牡丹学院,河南 洛阳 471023)

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常会庆(1974-),教授,博士,研究方向为固体废弃物处理。E-mail:hqchang@126.com。

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基金项目:国家自然科学基金(41571319)。


Effect of different excipients on passivation of heavy metals in pig manure composting
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(College of Agriculture,Henan University of Science and Technology,Luoyang Henan 471023)

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    摘要:

    以规模化猪场脱水猪粪为堆肥主料,采用自制好氧堆肥装置,探讨添加3%过磷酸钙、3%腐殖质和5%膨润土等辅料对堆肥过程中重金属形态变化与钝化效果的影响。结果表明,堆肥前猪粪原料中重金属含量依次为Zn>Cu>Cr>Pb>Cd,其中Pb、Zn的有效态含量较高,分别占总量的15.48%~40.30%、19.17%~34.58%。堆肥结束后,各处理有机质含量在50%~60%范围内,总P含量在0.64%~0.98%之间,pH稳定在6.80~7.40之间,EC值均低于4 mS/cm,满足腐熟堆肥的标准;各处理的重金属含量较堆肥前增加了7.91%~157.90%,表现出明显的“浓缩效应”,其中CK处理的Zn总量超标23.10%。添加不同辅料整体上促使各重金属向有效性较低的方向转化,但对各重金属的钝化表现并不一致。其中,3%腐殖质对Cu、Zn的钝化率分别为52.11%、32.11%;复合配料(3%过磷酸钙+3%腐殖质+5%膨润土)对Cr、Cd、Pb的钝化率分别为46.43%、47.05%、51.76%。堆肥主要参数与各有效态重金属的关系表明,堆肥主要理化参数与各重金属有效性之间存在一定的相关性。堆肥结束后,各处理堆肥产物的内梅罗污染指数表现为低,等级处于安全水平。

    Abstract:

    Dehydrated pig manure from a large-scale pig farm was utilized as the primary composting material,and a self-made aerobic composting device was employed to investigate the effects of 3% superphosphate,3% humus and 5% bentonite on the morphological changes and passivation effect of heavy metals during the composting process.The findings revealed that among the heavy metals in pig manure samples,Zn had the highest content,followed by Cu,Cr,Pb and Cd.Notably,before composting treatment,the contents of available Pb and available Zn were high,accounting for 15.48%-40.30% and 19.17%-34.58% of the total contents of Pb and Zn,respectively.Moreover,post-composting analysis demonstrated that organic matter content ranged between 50% and 60%,total P ranged between 0.64% and 0.98%,pH remained stable within the range of 6.80-7.40,and EC value was lower than 4 mS/cm,which met mature composting standards.The concentration of heavy metals in each treatment increased by 7.91%-157.90%,compared with before composting,showing an evident “relative concentration effect”.Specifically,the total amount of Zn in CK treatment exceeded standard levels by 23.10% after composting.The addition of various excipients facilitated the overall transformation of heavy metals towards reduced effectiveness,although the passivation performance varied for each individual metal.The passivation rates of Cu and Zn by 3% humus were 52.11% and 32.11%,respectively,and the passivation effect was good.The passivation rates of Cr,Cd and Pb by compound ingredients(3% superphosphate+3% humus+5% bentonite)were 46.43%,47.05% and 51.76%,respectively.There was a certain correlation between the main physical and chemical parameters of compost and the availability of heavy metals.The Nemero composting products from each treatment remained low and within safe levels.

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常会庆,阳沅橦,宋盼盼,黄琳琳.添加不同辅料对猪粪堆肥重金属钝化效果的影响[J].中国土壤与肥料,2024,(10):232-241.

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  • 收稿日期:2023-12-27
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  • 录用日期:2024-03-29
  • 在线发布日期: 2024-12-26
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