不同钝化剂对石灰性土壤重金属污染的修复效果研究
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作者单位:

(1.内蒙古农业大学资源与环境学院,内蒙古 呼和浩特 010018;2.内蒙古自治区土壤质量与养分资源重点实验室,内蒙古 呼和浩特 010018)

作者简介:

李静雪(2002-),硕士研究生,研究方向为土壤污染与修复技术。E-mail:1092633390@qq.com。

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基金项目:

基金项目:内蒙古自治区科技重大专项(2019ZD001);内蒙古自治区自然科学基金重大项目(2021ZD10)。


Study on the remediation effect of different passivators on heavy metal pollution in calcareous soil
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(1.College of Resources and Environmental Science,Inner Mongolia Agricultural University,Hohhot Inner Mongolia 010018;2.Inner Mongolia Key Laboratory of Soil Quality and Nutrient Resource,Hohhot Inner Mongolia 010018)

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    摘要:

    随着现代工业的迅速发展,土壤重金属污染已经成为全球环境治理的热点问题。我国北方广泛分布的石灰性土壤也面临这一问题。在众多修复技术中,原位钝化被认为是降低土壤中重金属有效性的最佳方法之一。为了探索不同钝化材料对石灰性土壤重金属污染修复的效果,以镉(Cd)污染石灰性土壤为研究对象,以小白菜为供试作物,通过室内盆栽试验研究添加浓度为1%(w/w)和3%(w/w)的粉煤灰、海泡石、氧化锰、三氧化二铁、生物炭、膨润土6种钝化剂对土壤中Cd的钝化效果和对植物生长的影响,结果表明:与不施加钝化剂(对照)相比,添加粉煤灰、海泡石和生物炭可以使植株鲜重提升2%~20.8%,生物炭、粉煤灰可以有效提升植株干重。不同钝化剂处理下小白菜叶片的SPAD值比对照提高了0.58%~5.8%,但未达到显著水平。添加钝化剂后土壤pH值均呈现升高的趋势。添加生物炭可显著提升土壤有机质含量,最高比对照提高44.5%。1%添加量下的粉煤灰、海泡石、生物炭和膨润土处理下,土壤可交换态镉含量较对照分别下降3.4%、11.6%、19.4%、14.2%;3%添加量的粉煤灰、海泡石、生物炭和膨润土处理下,土壤可交换态镉含量较对照分别下降7.3%、11.5%、23.8%、16.4%;铁锰氧化物结合态及有机物结合态的含量变化不明显;残渣态镉的比例呈现上升趋势。添加钝化剂可以有效降低植株体内Cd的累积,其中地上部Cd含量较对照降低了11.2%~21.4%、地下部分Cd含量较对照降低了1.2%~16.3%。综合来看,对石灰性土壤Cd污染钝化效果较好的是粉煤灰、海泡石、生物炭和膨润土,该研究结果为北方石灰性土壤重金属污染防治提供了科学依据。

    Abstract:

    With the rapid development of modern industry,soil heavy metal pollution has become a critical issue in global environmental governance. The widely distributed calcareous soil in northern China is also confronted with this challenge. Among numerous remediation techniques,in-situ passivation is recognized as one of the most effective methods for reducing the bioavailability of heavy metals in soil. To investigate the effects of different passivating agents on the remediation of heavy metal-contaminated calcareous soil,this study used Cd-contaminated calcareous soil as the study subject. Chinensis (Chinese cabbage) as the test crop, through indoor pot experiments,six passivators—fly ash,sepiolite,ferric oxide,manganese oxide,biochar,and bentonite—were applied at concentrations of 1% and 3% (w/w),respectively,to evaluate their passivation effects on soil Cd and impactson plant growth. The results showed that compared with the control,additions of fly ash,sepiolite,and biochar increased plant fresh weight by 2%-20.8%. Biochar,fly ash significantly improved plant dry weight. The SPAD values of Chinese cabbage leaves treated with different passivators was increased by 0.58%-5.8%,compared to the control,but the differences did not reach statistical significance. After passivator application,soil pH values exhibited an upward trend. Biochar significantly increased soil organic matter content,with a maximum increase of 44.5% relative to the control. Under the 1% application rate,fly ash,sepiolite,biochar,and bentonite reduced soil exchangeable Cd content by 3.4%,11.6%,19.4%,and 14.2%,respectively;at the 3% rate,these reductions were 7.3%,11.5%,23.8%,and 16.4%. Additionally,no significant variations were detected in the contents of iron-manganese oxide-bound and organic matter-bound Cd fractions,while the proportion of residual Cd showed an upward trend across most treatments. Passivator additions effectively reduced plant Cd accumulation,with aboveground Cd contents decreasing by 11.2%-21.4% and underground Cd contents decreasing by 1.2%-16.3%,compared to the control. Overall,fly ash,sepiolite,biochar,and bentonite demonstrated superior passivation effects on Cd pollution in calcareous soils,while ferric oxide and manganese oxide showed limited efficacy under the tested conditions. These findings provided a scientific basis for the targeted selection of passivators in the remediation of heavy metal pollution in calcareous soils of northern China.

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李静雪,刘美英,师泰龙,贾宇飞,许学慧.不同钝化剂对石灰性土壤重金属污染的修复效果研究[J].中国土壤与肥料123,2026,(3):185-191

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  • 收稿日期:2025-06-05
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  • 录用日期:2025-08-17
  • 在线发布日期: 2026-05-11
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